Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands

Abeer A. Faheim

doi:doi:10.11648/j.mc.20140203.11

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Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands

Abeer A. Faheim

Published in Modern Chemistry (Volume 2, Issue 3)

Received: 12 July 2014 Accepted: 11 August 2014 Published: 20 August 2014

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Abstract

Mononuclear binary and ternary complexes of UO22+ ion with N-salicylidene-4-Aminotoluene-3-sulfonic acid as primary ligand and 8-hydroxyquinoline as coligand have been prepared. The elemental analysis, molar conductance, IR and solid reflectance spectra in addition to the magnetic moment measurements, thermal study, XRD and SEM analysis were utilized to investigate the coordination behavior of these complexes. From the investigation data, all complexes have metal to ligand ratio of 1:1 and 1:1:1 with octahedral and dodecahedral geometry for binary and ternary complexes, respectively and the force constant, FU-O and bond length, RU-O were calculated. The thermal behavior of these complexes was investigated and the thermal decomposition pathways have been postulated showing that the final product is metal or metal oxide. Antimicrobial properties of the complexes have also been examined against Staphylococcus aureus (ATCC 25923), Streptococcus pyogenes (ATCC 19615), Pseudomonas fluorescens (S 97), Pseudomonas phaseolicola (GSPB 2828), Fusarium oxysporum and Aspergillus fumigatus. The corrosion inhibition of aluminum specimens in acidic solution was studied by weight loss method. The ternary complex, [UO2(HL)(8-Oqu)H2O] was found to be exhibits excellent inhibitory activity against the different microorganisms in addition to its corrosion inhibition efficiency towards Al-specimens in acidic solution more than the binary complex, [UO2(HL)NO3].2H2O.

Published in	Modern Chemistry (Volume 2, Issue 3)
DOI	10.11648/j.mc.20140203.11
Page(s)	19-28
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

8-Hydroxyquinoline, Mixed Ligand Complexes, Spectroscopic Characterization, Thermal Investigation, Acid Inhibition, Biological Study

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Abeer A. Faheim. (2014). Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Modern Chemistry, 2(3), 19-28. https://doi.org/10.11648/j.mc.20140203.11

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Abeer A. Faheim. Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Mod. Chem. 2014, 2(3), 19-28. doi: 10.11648/j.mc.20140203.11

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AMA Style

Abeer A. Faheim. Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Mod Chem. 2014;2(3):19-28. doi: 10.11648/j.mc.20140203.11

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@article{10.11648/j.mc.20140203.11,
  author = {Abeer A. Faheim},
  title = {Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands},
  journal = {Modern Chemistry},
  volume = {2},
  number = {3},
  pages = {19-28},
  doi = {10.11648/j.mc.20140203.11},
  url = {https://doi.org/10.11648/j.mc.20140203.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20140203.11},
  abstract = {Mononuclear binary and ternary complexes of UO22+ ion with N-salicylidene-4-Aminotoluene-3-sulfonic acid as primary ligand and 8-hydroxyquinoline as coligand have been prepared. The elemental analysis, molar conductance, IR and solid reflectance spectra in addition to the magnetic moment measurements, thermal study, XRD and SEM analysis were utilized to investigate the coordination behavior of these complexes. From the investigation data, all complexes have metal to ligand ratio of 1:1 and 1:1:1 with octahedral and dodecahedral geometry for binary and ternary complexes, respectively and the force constant, FU-O and bond length, RU-O were calculated. The thermal behavior of these complexes was investigated and the thermal decomposition pathways have been postulated showing that the final product is metal or metal oxide. Antimicrobial properties of the complexes have also been examined against Staphylococcus aureus (ATCC 25923), Streptococcus pyogenes (ATCC 19615), Pseudomonas fluorescens (S 97), Pseudomonas phaseolicola (GSPB 2828), Fusarium oxysporum and Aspergillus fumigatus. The corrosion inhibition of aluminum specimens in acidic solution was studied by weight loss method. The ternary complex, [UO2(HL)(8-Oqu)H2O] was found to be exhibits excellent inhibitory activity against the different microorganisms in addition to its corrosion inhibition efficiency towards Al-specimens in acidic solution more than the binary complex, [UO2(HL)NO3].2H2O.},
 year = {2014}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands
AU  - Abeer A. Faheim
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.mc.20140203.11
DO  - 10.11648/j.mc.20140203.11
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 19
EP  - 28
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20140203.11
AB  - Mononuclear binary and ternary complexes of UO22+ ion with N-salicylidene-4-Aminotoluene-3-sulfonic acid as primary ligand and 8-hydroxyquinoline as coligand have been prepared. The elemental analysis, molar conductance, IR and solid reflectance spectra in addition to the magnetic moment measurements, thermal study, XRD and SEM analysis were utilized to investigate the coordination behavior of these complexes. From the investigation data, all complexes have metal to ligand ratio of 1:1 and 1:1:1 with octahedral and dodecahedral geometry for binary and ternary complexes, respectively and the force constant, FU-O and bond length, RU-O were calculated. The thermal behavior of these complexes was investigated and the thermal decomposition pathways have been postulated showing that the final product is metal or metal oxide. Antimicrobial properties of the complexes have also been examined against Staphylococcus aureus (ATCC 25923), Streptococcus pyogenes (ATCC 19615), Pseudomonas fluorescens (S 97), Pseudomonas phaseolicola (GSPB 2828), Fusarium oxysporum and Aspergillus fumigatus. The corrosion inhibition of aluminum specimens in acidic solution was studied by weight loss method. The ternary complex, [UO2(HL)(8-Oqu)H2O] was found to be exhibits excellent inhibitory activity against the different microorganisms in addition to its corrosion inhibition efficiency towards Al-specimens in acidic solution more than the binary complex, [UO2(HL)NO3].2H2O.
VL  - 2
IS  - 3
ER  -

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Author Information

Abeer A. Faheim

Chemistry Department, Faculty of Science (Girl's), Al-Azhar University, Nasr-City, Cairo, Egypt, P.O.Box 11754

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APA Style

Abeer A. Faheim. (2014). Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Modern Chemistry, 2(3), 19-28. https://doi.org/10.11648/j.mc.20140203.11

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ACS Style

Abeer A. Faheim. Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Mod. Chem. 2014, 2(3), 19-28. doi: 10.11648/j.mc.20140203.11

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AMA Style

Abeer A. Faheim. Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands. Mod Chem. 2014;2(3):19-28. doi: 10.11648/j.mc.20140203.11

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@article{10.11648/j.mc.20140203.11,
  author = {Abeer A. Faheim},
  title = {Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands},
  journal = {Modern Chemistry},
  volume = {2},
  number = {3},
  pages = {19-28},
  doi = {10.11648/j.mc.20140203.11},
  url = {https://doi.org/10.11648/j.mc.20140203.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20140203.11},
  abstract = {Mononuclear binary and ternary complexes of UO22+ ion with N-salicylidene-4-Aminotoluene-3-sulfonic acid as primary ligand and 8-hydroxyquinoline as coligand have been prepared. The elemental analysis, molar conductance, IR and solid reflectance spectra in addition to the magnetic moment measurements, thermal study, XRD and SEM analysis were utilized to investigate the coordination behavior of these complexes. From the investigation data, all complexes have metal to ligand ratio of 1:1 and 1:1:1 with octahedral and dodecahedral geometry for binary and ternary complexes, respectively and the force constant, FU-O and bond length, RU-O were calculated. The thermal behavior of these complexes was investigated and the thermal decomposition pathways have been postulated showing that the final product is metal or metal oxide. Antimicrobial properties of the complexes have also been examined against Staphylococcus aureus (ATCC 25923), Streptococcus pyogenes (ATCC 19615), Pseudomonas fluorescens (S 97), Pseudomonas phaseolicola (GSPB 2828), Fusarium oxysporum and Aspergillus fumigatus. The corrosion inhibition of aluminum specimens in acidic solution was studied by weight loss method. The ternary complex, [UO2(HL)(8-Oqu)H2O] was found to be exhibits excellent inhibitory activity against the different microorganisms in addition to its corrosion inhibition efficiency towards Al-specimens in acidic solution more than the binary complex, [UO2(HL)NO3].2H2O.},
 year = {2014}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Binary and Ternary Dioxouranium (VI) Complexes with Oxygen, Nitrogen and Sulphur Donor Ligands
AU  - Abeer A. Faheim
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.mc.20140203.11
DO  - 10.11648/j.mc.20140203.11
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 19
EP  - 28
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20140203.11
AB  - Mononuclear binary and ternary complexes of UO22+ ion with N-salicylidene-4-Aminotoluene-3-sulfonic acid as primary ligand and 8-hydroxyquinoline as coligand have been prepared. The elemental analysis, molar conductance, IR and solid reflectance spectra in addition to the magnetic moment measurements, thermal study, XRD and SEM analysis were utilized to investigate the coordination behavior of these complexes. From the investigation data, all complexes have metal to ligand ratio of 1:1 and 1:1:1 with octahedral and dodecahedral geometry for binary and ternary complexes, respectively and the force constant, FU-O and bond length, RU-O were calculated. The thermal behavior of these complexes was investigated and the thermal decomposition pathways have been postulated showing that the final product is metal or metal oxide. Antimicrobial properties of the complexes have also been examined against Staphylococcus aureus (ATCC 25923), Streptococcus pyogenes (ATCC 19615), Pseudomonas fluorescens (S 97), Pseudomonas phaseolicola (GSPB 2828), Fusarium oxysporum and Aspergillus fumigatus. The corrosion inhibition of aluminum specimens in acidic solution was studied by weight loss method. The ternary complex, [UO2(HL)(8-Oqu)H2O] was found to be exhibits excellent inhibitory activity against the different microorganisms in addition to its corrosion inhibition efficiency towards Al-specimens in acidic solution more than the binary complex, [UO2(HL)NO3].2H2O.
VL  - 2
IS  - 3
ER  -

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